0th law of thermodynamics to define temperature, heat conduction, first law (conservation of energy, ΔU = Q – W), second law of thermodynamics (heat bath diagrams to illustrate heat engines and refrigerator).
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% Author: Izaak Neutelings (February 2019) \documentclass[border=3pt,tikz]{standalone} \usepackage{amssymb,amsmath,physics} \usepackage{tikz} \usetikzlibrary{calc,patterns,decorations.pathmorphing} \tikzset{>=latex} \colorlet{mydarkblue}{blue!50!black} \colorlet{myblue}{blue!30} \colorlet{mydarkred}{red!60!black} \colorlet{myred}{red!30} \colorlet{mydarkgreen}{green!60!black} \colorlet{mygreen}{green!30} \colorlet{mydarkorange}{yellow!40!red} \colorlet{myorange}{yellow!80!red} \colorlet{myyellow}{yellow!80} \colorlet{mygrey}{black!15} \colorlet{mydarkgrey}{black!50} \tikzstyle{bath}=[draw=blue!40!black,top color=blue!10, bottom color=blue!20,shading angle=30,thick,rounded corners=1] \tikzstyle{source}=[draw=red!50!black,top color=red!20, bottom color=red!30,shading angle=30,thick,rounded corners=1] \tikzstyle{conductor}=[draw=black!40,top color=black!8, bottom color=black!20,shading angle=30,thick,rounded corners=1] \tikzstyle{insulator}=[draw=yellow!40!red!80,top color=yellow!90!red!80, bottom color=yellow!80!red!80,shading angle=10,thick,rounded corners=1] \tikzstyle{C1}=[draw=black!80!red!70,top color=black!40!red!10, bottom color=black!80!red!20,shading angle=30,thick] \tikzstyle{C2}=[draw=black!90!green!70,top color=black!50!green!8, bottom color=black!90!green!20,shading angle=30,thick] \tikzstyle{C3}=[draw=black!80!yellow!80,top color=black!20!yellow!10, bottom color=black!80!yellow!20,shading angle=30,thick] \begin{document} % 0th LAW \begin{tikzpicture} \def\dl{0.027} \draw[bath] (-0.3-\dl,1.5) rectangle ++(-1,-1) node[midway] {A}; \draw[bath] ( 0.3+\dl,1.5) rectangle ++( 1,-1) node[midway] {B}; \draw[bath] (-1,-\dl) rectangle ++(2,-0.6) node[midway] {C}; \draw[insulator] (-0.3,0) rectangle ++(0.6,1.7) node[midway] {I}; \draw[conductor] (-0.3-\dl,0) rectangle ++(-1,0.5-\dl); \draw[conductor] ( 0.3+\dl,0) rectangle ++(+1,0.5-\dl); \path[draw,<->,thick,mydarkred, decorate,decoration={snake,amplitude=1,segment length=4,pre length=5,post length=5}] (-0.7,-0.1) --++ (0,0.7); \draw[<->,thick,mydarkred, decorate,decoration={snake,amplitude=1,segment length=4,pre length=5,post length=5}] ( 0.7,-0.1) --++ (0,0.7); \end{tikzpicture} % 0th LAW \begin{tikzpicture} \def\dl{0.027} \draw[bath] (-0.3-\dl,1.5) rectangle ++(-1,-1) node[midway] {A}; \draw[bath] ( 0.3+\dl,1.5) rectangle ++( 1,-1) node[midway] {B}; \draw[bath] (-1,-\dl) rectangle ++(2,-0.6) node[midway] {C}; \draw[conductor] (-0.3,1.5) rectangle ++(0.6,-1); \draw[insulator] (-1.4,0) rectangle ++(2.8,0.5-\dl) node[midway] {I}; \end{tikzpicture} % HEAT SOURCE & SINK \begin{tikzpicture}[scale=1.5] \def\l{0.8} \def\dl{0.0185} \draw[source] (-\l-\dl,-0.5) rectangle ++(-1.2,1) node[midway,align=center] {heat\\[-2pt]source}; \draw[bath] ( \l+\dl,-0.5) rectangle ++( 1.2,1) node[midway,align=center] {heat\\[-2pt]sink}; \draw[conductor,rounded corners=0] (-\l,-0.2) rectangle ++(2*\l,0.4); \draw[->,thick,mydarkred, decorate,decoration={snake,amplitude=2,segment length=8,pre length=1,post length=5}] (-0.7*\l,0) --++ (1.4*\l,0); \end{tikzpicture} % SERIAL \begin{tikzpicture}[scale=1.5] \def\l{1.6} \def\dl{0.0185} \draw[source] (-\l/2-\dl,-0.5) rectangle ++(-1.2,1) node[midway,align=center] {heat\\[-2pt]source}; \draw[bath] ( \l/2+\dl,-0.5) rectangle ++( 1.2,1) node[midway,align=center] {heat\\[-2pt]sink}; \draw[C1] (-\l/2,-0.2) rectangle ++(\l/3-\dl,0.4) node[midway,scale=0.9] {C$_1$}; \draw[C2] (-\l/6,-0.2) rectangle ++(\l/3,0.4) node[midway,scale=0.9] {C$_2$}; \draw[C3] (\l/6+\dl,-0.2) rectangle ++(\l/3-\dl,0.4) node[midway,scale=0.9] {C$_3$}; \end{tikzpicture} % PARALLEL \begin{tikzpicture}[scale=1.5] \def\l{1.5} \def\dl{0.0185} \draw[source] (-\l/2-\dl,-0.5) rectangle ++(-1.2,1) node[midway,align=center] {heat\\[-2pt]source}; \draw[bath] ( \l/2+\dl,-0.5) rectangle ++( 1.2,1) node[midway,align=center] {heat\\[-2pt]sink}; \draw[C1] (-\l/2, 0.185) rectangle ++(\l,0.28) node[midway,scale=0.9] {C$_1$}; \draw[C2] (-\l/2,-0.14) rectangle ++(\l,0.28) node[midway,scale=0.9] {C$_2$}; \draw[C3] (-\l/2,-0.185) rectangle ++(\l,-0.28) node[midway,scale=0.9] {C$_3$}; \end{tikzpicture} % PARALLEL \begin{tikzpicture}[xscale=0.5,yscale=0.25] \draw[bath] (-2,-2) rectangle ++(4,4) node[midway,align=center,scale=1] {$\Delta U$}; \node[below] at (0,-2) {system}; \draw[<-,very thick,red!70!black] (-1.2,0) to[out=170,in=20]++ (-2,0) node[left] {$Q$}; \draw[->,very thick,green!60!black] ( 1.2,0) to[out=20,in=170]++ ( 2,0) node[right] {$W$}; \end{tikzpicture} % HEAT SOURCE & SINK \begin{tikzpicture} \def\H{.8} \def\W{3.2} \def\L{1.6} \def\dl{0.0185} \coordinate (H) at (0, \L/2); \coordinate (C) at (0,-\L/2); \draw[bath] (C)++(-.4*\W,0) rectangle ++(\W,-\H) node[midway,align=center] {cold reservoir, $T_\text{C}$}; \draw[mydarkblue,top color=red!22,bottom color=blue!10] (H) ++ (-.15*\W,0) -- (-.15*\W,.2-\L/2) --++ (-.2,0) -- (0,-.2-\L/2) -- (.2+.15*\W,.2-\L/2) --++ (-.2,0) -- % large arrow: cold reservoir (.15*\W,.1*\L) to[out=-90,in=180] (.5*\W,-.2*\L) --++ (0,-.15) --++ (.25,.3) coordinate (W) --++ (-.25,.3) --++ (0,-.15) % small arrow: work to[out=180,in=-90] (.5+.1*\W,.2+.05*\L) -- (.5+.1*\W,\L/2); \draw[source] (H)++(-.4*\W,0) rectangle ++(\W,\H) node[midway,align=center] {hot reservoir, $T_\text{H}$}; \node[red,right=4,below=1] at (H) {$Q_\text{h}$}; \node[mydarkgreen,right=0] at (W) {$W$}; \node[blue,above=1] at (C) {$\abs{Q_\text{c}}$}; \end{tikzpicture} % REFRIGERATOR \begin{tikzpicture} \def\H{.8} \def\W{3.2} \def\L{1.6} \def\dl{0.0185} \coordinate (H) at (0, \L/2); \coordinate (C) at (0,-\L/2); \draw[source] (H)++(-.4*\W,0) rectangle ++(\W,\H) node[midway,align=center] {hot reservoir, $T_\text{H}$}; \draw[mydarkblue,top color=red!22,bottom color=blue!10] (C) ++ (-.2*\W,0) -- (-.2*\W,-.2+\L/2) --++ (-.2,0) -- (0,.2+\L/2) -- (.2+.2*\W,-.2+\L/2) --++ (-.2,0) -- % large arrow: cold reservoir (.2*\W,.1*\L) to[out=-90,in=180] (.45*\W,-.1*\L) --++ (-0.25,-0.15) coordinate (W) --++ (0.25,-0.15) % small arrow: work to[out=180,in=-90] (.2*\W-0.3,.05*\L) -- (.2*\W-0.3,-\L/2); % (.15*\W,.1*\L) to[out=-90,in=180] (.5*\W,-.2*\L) --++ % (-.25,.17) coordinate (W) --++ (.25,.17) % small arrow: work % to[out=180,in=-90] (.5+.1*\W,.2+.05*\L) -- (.5+.1*\W,\L/2); \draw[bath] (C)++(-.4*\W,0) rectangle ++(\W,-\H) node[midway,align=center] {cold reservoir, $T_\text{C}$}; \node[red,right=2,below=-1] at (H) {$Q_\text{h}$}; \node[mydarkgreen,right=7] at (W) {$W$}; \node[blue,left=4,above=1] at (C) {$\abs{Q_\text{c}}$}; \end{tikzpicture} \end{document}
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